An electron-beam-grafted ETFE alkaline anion-exchange membrane in metal-cation-free solid-state alkaline fuel cells

An electron-beam-grafted ETFE alkaline anion-exchange membrane in metal-cation-free solid-state alkaline fuel cells

A novel, physically strong, quaternary-ammonium-functionalised radiation-grafted ETFE alkaline anion-exchange membrane (AAEM) has been developed for application in fuel cells without undesirable addition of MOH into the anode fuel stream, thereby facilitating stable performances and long term operational lifetimes. A promising H2/O2 fuel cell peak power performance of 130 mW cm -2 was obtained ...

Polysulfone-based Anion Exchange Membranes for Potential Application in Solid Alkaline Fuel Cells

In present research work, anion exchange membranes based on quaternized polysulfone with ammonium cation moieties (QAPSF) were prepared by chloromethylation, amination and alkalization. The chloromethylated polysulfone were characterized by 1HNMR spectroscopy and functionalization degree was determined according to peak area integration. Ion transport properties (ionic conductivity, ion exchang...

Poly (Ether Ether Ketone) Based Anion Exchange Membrane for Solid Alkaline Fuel Cell: A Review

Solid alkaline fuel cell is employed by polymer anion exchange membrane (AEM) that is permeable to hydroxide ion. A number of polymers have been proposed for AEM which include polysulfone (PSF), poly (phenylene oxide) (PPO), and poly (ether ether ketone) (PEEK). The purpose of this paper was to conduct a critical review on the development of PEEK polymer as AEM, particu...

Ionic Copolymers for Alkaline Anion Exchange Membrane Fuel Cells (AAEMFCs)

Alkaline anion-exchange radiation-grafted membranes for possible electrochemical application in fuel cells

Vinylbenzyl chloride was grafted onto PVDF and FEP polymer films using the radiation-grafting methodology. Subsequent reaction with trimethylamine and ion-exchange with potassium hydroxide yields alkaline anion-exchange membranes that are capable of conducting hydroxide ions; such membranes may be suitable for use in low temperature direct methanol fuel cells for portable devices. The PVDF base...